/de/research/projects/2-04/highlights/MolStructDynamics-2011.html
2-04 Molecular Vibrational and Reaction Dynamics in the Condensed Phase
Project coordinator(s): E. Nibbering
Recent Highlights

Ultrafast molecular structural dynamics in the condensed phase

Highlights of project 2-04 in 2011

Date Highlight  Links to more Information
   
3 November 2011

Headline news:
In a collaboration between the Elsaesser/Nibbering (MBI) and Levinger (Colorado State University, USA) teams the vibrational energy migration pathways in phospholipid reverse micelles are investigated with ultrafast mid-IR pump-probe spectroscopy.


Link to original paper

 

One sentence summary:
The key role of hydration for mediating ultrafast energy migration and dissipation in phospholipids self-assembled into reverse micelles is exemplified by determination of the rate of resonant excitation transfer between phosphate groups and by introducing a water pool as a confined heat sink for excess energy.

More details on page of subproject 1

 



Contact: Thomas Elsaesser
Contact: Erik T. J. Nibbering
Contact: Nancy E. Levinger

 


Nancy and René discussing the results on the phospholipid reverse micelles

 

 

External funding by:

National Science Foundation (Grant CHE 0628260)


European Research Council Advanced Grant under the European Union´s Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement no. 247051

Link to ERC
   
29 September 2011

Headline news:
In a collaboration between the Nibbering (MBI) and Batista (Yale University, USA) teams the solvent-induced OH stretching frequency shifts of a prototypical photoacid dissolved in nonpolar/weakly polar solvents are explained in a combined transient IR spectroscopic and quantum chemical calculational study.


Link to original paper

 

One sentence summary:
The vibrational frequency shifts of the OH-stretching mode of uncomplexed 2-naphthol observed with femtosecond IR spectrosocpy in the electronic ground and excited states are explained using a perturbative solute-solvent interaction model and parametrized by (TD-)DFT quantum chemcial calculations.

More details on page of subproject 2

 



Contact: Erik T. J. Nibbering
Contact: Victor S. Batista

 


Skype conference with the Yale group.

 

 

External funding by:

National Science Foundation (Grant CHE 0911520)


Fonds Québecois de la Recherche sur la Nature et les Technologies

 
   
12 May 2011

Headline news:
In a joint collaboration between the Elsaesser/Nibbering (MBI) and Temps (Christian Albrechts Universität zu Kiel) teams the N-H stretching spectroscopy of Guanosine-Cytidine base pairs is unraveled.


Link to original paper (Published in the Shaul Mukamel Festschrift)

 

One sentence summary:
Linear FT-IR and 2D-IR photon echo spectroscopy provide insight into the dynamics and couplings of the N-H stretching manifold of GC base pairs in solution.

More details on page of subproject 1

 



Contact: Erik T. J. Nibbering
Contact: Thomas Elsaesser
Contact: Friedrich Temps

 

 

External funding by:


European Research Council under the European Union´s Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement no. 247051


German Science Foundation


Link to ERC
   
5 May 2011

Headline news:
In a joint collaboration between the MBI and the Freie Universität Berlin the complexation chemistry of 2-chloro-4-nitrophenol with acetate in dichloromethane has been surveyed in a combined UV/NMR heterospectral correlation approach with unsurpassed detail.


Link to original paper

 

One sentence summary:
Two-dimensional heterospectral UV/NMR correlation spectroscopy provides insight into the composition of hydrogen-bonded complexes in dichloromethane solution.

More details on page of subproject 1

 



Contact: Peter M. Tolstoy
Contact: Erik T. J. Nibbering
Contact: Thomas Elsaesser

 

 

External funding by:


European Research Council under the European Union´s Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement no. 247051


Link to ERC
   
10 February 2011

Headline news:
2D-IR photon echo spectroscopy on DNA oligomers monitor individual line broadening and vibrational energy transfer of the NH-stretching modes of the DNA bases.


Link to original paper

 

One sentence summary:
Ultrafast 2D-IR spectroscopy of the NH-stretching bands of adenine–thymine base pairs in DNA oligomers enable to distinguish different line broadening as well as energy transfer..

More details on page of subproject 1

 



Contact: Thomas Elsaesser

 

 

External funding by:


European Research Council under the European Union´s Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement no. 247051


Link to ERC