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/de/research/projects/2-04/highlights/MolStructDynamics-2003.html
2-04 Molecular Vibrational and Reaction Dynamics in the Condensed Phase
Project coordinator(s): E. Nibbering
Recent Highlights

Ultrafast molecular structural dynamics in the condensed phase

Highlights of project 2-04 in 2003

DateHighlight  Links to more Information
  
28 November 2003

Headline news:
In the SFB450-B2 project run by the Elsaesser/Nibbering team (Max Born Institut for Nonlinear Optics and Short Pulse Spectroscopy) first two colour infrared pump-probe measurements reveal how vibrational modes mutually interact in hydrogen bonds.


Link to original paper

 

One sentence summary:
Two colour infrared pump-probe measurements on acetic acid dimer show the importance of anharmonic coupling between and the involvement of different vibrational modes in this important model system for hydrogen bonding.

More details on page of subproject 1

 


Karsten Heyne analysing the two colour pump-probe data on acetic acid dimer.


Contact: Erik T. J. Nibbering
Contact: Thomas Elsaesser

 External funding by:


German Science Foundation: SFB450-B2 (Sonderforschungsbereich 450 "Analyse und Steuerung ultraschneller photoinduzierter Reaktionen")

Link to SFB450 web-page
  
7 November 2003

Headline news:
In the SFB450-B2 project run by the Elsaesser/Nibbering team (Max Born Institut for Nonlinear Optics and Short Pulse Spectroscopy) photon echo results have been reported on hydrogen bond dynamics in acetic acid dimer, an important model system for coupled hydrogen bonds in biomolecular structures.


Link to original paper

 

One sentence summary:
An infrared photon-echo study of the O-H stretching band of acetic acid dimer reveals the dominant role of multi-level coherence interferences in the macroscopic polarization decay.

More details on page of subproject 1

 


Nils Huse measuring the photon echo data on acetic acid dimer.


Contact: Erik T. J. Nibbering
Contact: Thomas Elsaesser

 External funding by:


German Science Foundation: SFB450-B2 (Sonderforschungsbereich 450 "Analyse und Steuerung ultraschneller photoinduzierter Reaktionen")

Link to SFB450 web-page
  
18 July 2003

Headline news:
Members of the Nibbering team (Max Born Institut for Nonlinear Optics and Short Pulse Spectroscopy) in collaboration with the Pines team (Ben-Gurion University of the Negev) observe bimodal proton transfer dynamics in acid-base neutralization reactions in water.

Pressemitteilung
"Ab jetzt bist du sauer!"
Säuren beim Reagieren zusehen

 

One sentence summary:
Bimodal reaction dynamics, as observed in femtosecond infrared measurements on proton transfer reactions in acid-base pairs in water, demand refinement of the established Eigen-Weller mechanism.

Press Release
"From now on you are sour"
Looking at reacting acids

 

Summary showing the essence of the work

Persbericht
"Vanaf nu reageer je zuur!"
Kijken naar reagerende zuren

 

Link to original paper

Comunicato stampa
"Da questo momento siate acidi!"
Osservare il movimento dei protoni durante reazioni chimiche

 


Link to Perspective by Mark A. Johnson


Two fast studies of liquid water

 


The team members (left to right): Ben-Zion (Oleg) Magnes, Ehud Pines, Erik T. J. Nibbering and Matteo Rini

Pressemitteilung

 

 

More details on page of subproject 2

 

External funding by:


German Science Foundation: DFG NI 492/2-2 (Schwerpunktprogram "Femtosekunden-Spektroskopie elementarer Anregungen in Atomen, Molekülen und Clustern")


German-Israeli Foundation for Scientific Research and Development: GIF 722/01


LIMANS Cluster of Large Scale Facilities: MBI000228


Contact: Erik T. J. Nibbering

  
10 July 2003

Headline news:
"Carl-Ramsauer Preis" für Dr. Jens Stenger

Physiker des Max-Born-Instituts erhält Preis für die Untersuchung von Wasserstoffbrücken.

Pressemitteilung
Was die lebendige Welt im Innersten zusammenhält
  Dr. Jens Stenger in full action at the Carl Ramsauer Preisverleihung.
The Carl Ramsauer prizewinners in one row.
Official flyer announcing 2003 Carl Ramsauer prize winners

Carl Ramsauer prize winners on the official site of the Physikalische Gesellschaft zu Berlin
  
12 March 2003 Headline news:
In a joint project between the Nibbering team (Max Born Institut for Nonlinear Optics and Short Pulse Spectroscopy) and the Fidder team (Uppsala Universitet) competing ultrafast relaxation channels are observed in optically induced chemical reaction dynamics of the photochromic switch spiropyran.

Link to original paper
 One sentence summary:
Ultrafast internal conversion to the spiropyran ground state is found to be an efficient relaxation channel competing with the photochemically induced ring-opening reaction to merocyanine.
More details on page of subproject 4
 
Contact: Erik T. J. Nibbering
 


Matteo Rini, Henk Fidder together with Omar F. Mohammed in the femtosecond application laboratory.

 
 External funding by:


LIMANS Cluster of Large Scale Facilities: MBI000237


German Science Foundation: DFG NI 492/2-2 (Schwerpunktprogram "Femtosekunden-Spektroskopie elementarer Anregungen in Atomen, Molekülen und Clustern")
 
  
28 February 2003 Headline news:
In the SFB450-B2 project run by the Elsaesser/Nibbering team (Max Born Institut for Nonlinear Optics and Short Pulse Spectroscopy) new results have been reported on hydrogen bond dynamics in acetic acid dimer, an important model system for coupled hydrogen bonds in biomolecular structures.

Link to original paper
 One sentence summary:
The cyclic dimer of deuterated acetic acid, an important model system for hydrogen-bonded units of biomolecules, shows, upon excitation of the O–D stretching mode, coherent nuclear motions along several anharmonically coupled intermolecular low-frequency modes of the dimer.
More details on page of subproject 1
 
Karsten Heyne fitting the acetic acid dimer pump-probe data.

Contact: Erik T. J. Nibbering
Contact: Thomas Elsaesser
 External funding by:


German Science Foundation: SFB450-B2 (Sonderforschungsbereich 450 "Analyse und Steuerung ultraschneller photoinduzierter Reaktionen")

Link to SFB450 web-page
  
15 January 2003 Headline news:
A new procedure to simulate multidimensional nonlinear vibrational spectra based on electronic structure ab initio calculations has been developed by Jens Dreyer in collaboration with the group of Shaul Mukamel (University of Rochester / UC Irvine).

Link to original paper
 One sentence summary:
Analysis of a complete set of simulated one- and two-color multidimensional infrared spectra, which provide new insight into structural and dynamical properties of molecules and chemical reactions with ultrafast time resolution, shows distinct and direct signatures of anharmonicities, mode couplings, Fermi resonances, and relative transition dipole moments.
More details on page of subproject 5
  
Contact: Jens Dreyer